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教授

党延峰

  • 职称:教授(博导)
  • 出生年月:
  • 专业:有机化学&理论与计算化学
  • Email:yanfeng.dang@tju.edu.cn
  • 课题组网址:
个人简介

2022.07–至今 天津大学化学系 教授(博导)

2021.01–2022.06 天津大学化学系 英才副教授 (博导)

2015.11–2022.06 天津大学化学系 副教授

2010.09–2015.06 中国科学院大学化学学院(博士)

2006.09–2010.06 河南大学化学化工学院 (学士)

主要研究方向

(1)有机反应和有机金属均相催化反应的分子机制研究 (Comput. and Exptl.)

(2)新型过渡金属催化反应的理性优化设计及合成研究 (Comput. and Exptl.)

主持科研项目

(1) 国家自然科学基金面上项目:22073067,项目名称:双金属协同催化的不对称烯丙基取代反应机理的理论研究,直接经费:63.00万元,项目起止日期:2021.1-2024.12

(2) 国家自然科学基金面上项目:21673156,项目名称:钌催化的炔烃水合还原反应的机理研究及新催化体系的优化设计,直接经费: 65.00万元,项目起止年月:2017.1-2020.12

(3) 天津大学北洋青年学者项目:过渡金属催化的C–H活化/C–C偶联反应的机理研究,经费40.00万元,项目起止年月:2017.1-2020.12

(4) 天津自然科学基金青年项目:钯-胺/醛协同催化的C(sp3)–H活化/C–C偶联反应的机理研究,直接经费:6.00万元,项目起止年月:2017.04-2020.03

代表性研究论文

[1] Bo Li (本科生), Hui Xu, Yanfeng Dang*, K. N. Houk* Dispersion and steric effects on enantio-/diastereoselectivities in synergistic dual transition-metal catalysis. J. Am. Chem. Soc. 2022, 144, 1971-1985.

[2] Lu Xiao, Xin Chang, Hui Xu, Qi Xiong, Yanfeng Dang*, Chun-Jiang Wang* Cooperative catalyst-enabled regio- and stereodivergent synthesis of α-quaternary α-amino acids via asymmetric allylic alkylation of aldimine esters with racemic allylic alcohols. Angew. Chem. Int. Ed. 2022, 61, e20221294.

[3] Hui Xu, Bo Li, Zheyuan Liu, Yanfeng Dang* Mechanistic origins of stereodivergence in asymmetric cascade allylation and cyclization reactions enabled by synergistic Cu/Ir catalysis. ACS Catal. 2021, 11, 9008-9021.

[4] Bo Li (本科生), Yuli Li (本科生), Yanfeng Dang,* K. N. Houk* Post-transition state bifurcation in iron-catalyzed arene aminations. ACS Catal. 2021, 11, 6816-6824. (IF: 13.700)

[5] Zheyuan Liu, Xiaojiao Jin, Yanfeng Dang* Mechanistic studies of copper(I)-catalyzed stereoselective [2,3]-sigmatropic rearrangements of diazoesters with allylic iodides/sulfides. ACS Catal. 2021, 11, 691-702.

[6] Qianwei Chen, Yanhui Shi*, Yanfeng Dang*, and Changsheng Cao* et al. Suzuki–Miyaura Cross-Coupling of Sulfoxides. ACS Catal. 2020, 10, 8168-8176.

[7] Wenhui Feng, Tianyang Wang, Dongzhi Liu, Xiaotai Wang,* Yanfeng Dang* Mechanism of the palladium-catalyzed C(sp3)-H arylation of aliphatic amines: Unraveling the crucial role of silver(I) additives. ACS Catal. 2019, 9, 6672-6680.

[8] Qianwei Chen, Yanhui Shi*, Yanfeng Dang*, Changsheng Cao* et al. Sonogashira cross-coupling of aryltrimethylammonium salts. ACS Catal. 2019, 9, 3730-3736.

[9] Wenjing Liu, Xiaotai Wang,* Yanfeng Dang* et al. How does palladium–amino acid cooperative catalysis enable regio- and stereoselective C(sp3)-H functionalization in aldehydes and ketones? A DFT mechanistic study. ACS Catal. 2018, 8, 7698-7709.

[10] Ke Yang, Yanfeng Dang*, Debabrata Maiti*, Haibo Ge* et al. Ligand-promoted palladium-catalyzed β-methylene C-H arylation of primary aldehydes. Chem. Sci. 2022, 13, 5938-5943.

[11] Lu Xiao, Bo Li, Yanfeng Dang*, Xiu-Qin Dong*, Chun-Jiang Wang* et al. Stereodivergent synthesis of enantioenriched azepino[3,4,5-cd]-indoles via cooperative Cu/Ir-catalyzed asymmetric allylic alkylation and intramolecular Friedel-Crafts reaction. Chem. Sci. 2022, 13, 4801-4812.

[12] Cheng Wang, Yunfeng Deng*, Yanfeng Dang*, Rongjin Li*, Yanhou Geng et al. High-yield and sustainable synthesis of quinoidal compounds assisted by keto-enol tautomerism. Chem. Sci. 2021, 12, 9366-9371.

[13] Qi Cheng, Wenjing Liu,* Yanfeng Dang* Insights into the mechanism and regioselectivity in Ni-catalysed redox-relay migratory hydroarylation of alkenes with arylborons. Chem. Commun. 2021, 57, 13610?13613. (IF: 6.065)

[14] Ning Zhao, Xiaojiao Jin, Yanfeng Dang* Exploring the pivotal role of silver(I) additives in palladium-catalyzed NH2-directed C(sp3)-H arylation reactions. Chin. Chem. Lett. 2021, 32, 3980–3983.

[15] Qi Cheng, Yanfeng Dang* Mechanistic studies of nickel-catalyzed hydroarylation of styrenes. Org. Lett. 2020, 22, 8998-9003.

[16] Xiaojiao Jin, Yanfeng Dang* et al. Origins of unconventional γ-site selectivity in palladium-catalyzed C(sp3)-H activation and arylation of aliphatic alcohols. Org. Lett. 2020, 22, 1464–1468. (IF: 6.072)

[17] Zheyuan Liu, Yanfeng Dang*, Zhi-Xiang Wang* et al. DFT mechanistic account for the site selectivity of electron-rich C(sp3)-H bond in the manganese-catalyzed aminations. Org. Lett. 2020, 22, 453–457.

[18] Yanfeng Dang, Zhi-Xiang Wang* et al. Unveiling secrets of overcoming the “heteroatom problem”in palladium-catalyzed aerobic C-H functionalization of heterocycles: A DFT mechanistic study. J. Am. Chem. Soc. 2016, 138, 2712-2723.

[19] Yanfeng Dang, Zhi-Xiang Wang* et al. Mechanistic insight into ketone α-alkylation with unactivated olefins via C-H activation promoted by metal-organic cooperative catalysis (MOCC): Enriching the MOCC chemistry. J. Am. Chem. Soc. 2015, 137, 6279-6291.

[20] Yanfeng Dang, Zhi-Xiang Wang*, Xiaotai Wang* et al. The mechanism of a ligand-promoted C(sp3)-H activation and arylation reaction via palladium catalysis: Theoretical demonstration of a Pd(II)/Pd(IV) redox manifold. J. Am. Chem. Soc. 2015, 137, 2006-2014.

[21] Yanfeng Dang, Zhi-Xiang Wang*, Xiaotai Wang* et al. A computational mechanistic study of an unprecedented Heck-type relay reaction: Insight into the origins of regio- and enantioselectivities. J. Am. Chem. Soc. 2014, 136, 986-998.

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